Issue 22, 1997

Enantiospecific total synthesis of (+)-2-pupukeanone

Abstract

The first total synthesis of chiral 2-pupukeanone (+)-4, starting from R-carvone (–)-7 employing a 5-exo-trig radical cyclisation as the key reaction for the construction of the tricyclic isotwistane carbon framework, is described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 3293-3294

Enantiospecific total synthesis of (+)-2-pupukeanone

A. Srikrishna and T. Jagadeeswar Reddy, J. Chem. Soc., Perkin Trans. 1, 1997, 3293 DOI: 10.1039/A706321K

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