SCHEDULED MAINTENANCE
The stereochemistry of the antiviral metabolite (–)-virantmycin has been determined by NOE difference spectroscopy to be 2R,3R. This reverses an earlier stereochemical proposal for C-2. NOEs from a slowly exchanging hydroxy proton in a synthetic intermediate provided the key stereochemical information.
C. M. Pearce and J. K. M. Sanders, J. Chem. Soc., Perkin Trans. 1, 1990, 409 DOI: 10.1039/P19900000409
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