SCHEDULED MAINTENANCE
The reaction of some tertiary allylamines with dimethyl acetylenedicarboxylate in acetonitrile results in the formation of 1 : 1 adducts via[3,3] rearrangement of the allyl group from nitrogen to carbon.
K. A. Kandeel and J. M. Vernon, J. Chem. Soc., Perkin Trans. 1, 1987, 2023 DOI: 10.1039/P19870002023
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