Nitration, bromination, and reaction with acetic anhydride, with halogen acids, and with sodium alkoxide, have been explored in the 1,2-benzisoxazole 2-oxide series, The nitration proceeded by simple substitution; the other reactions took place with rupture of the heterocyclic ring. Deoxygenation to the 1,2-benzisoxazoles could be accomplished, under forcing conditions.
A. J. Boulton, P. G. Tsoungas and C. Tsiamis, J. Chem. Soc., Perkin Trans. 1, 1987, 695 DOI: 10.1039/P19870000695
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