Issue 0, 1986

Formation of 3(4→18)-abeo-aphidicolenes via cyclopropyl intermediates. X-Ray molecular structure of 3(4→18)-abeo-17-noraphidicol-2,18(4)-dien-16-one

Abstract

The participation of the Δ2 double bond in the displacement of C-18 substituents on the diterpenoid aphidicolin skeleton has been shown to lead to ring expansion with the probable intervention of a cyclopropyl intermediate.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 639-642

Formation of 3(4→18)-abeo-aphidicolenes via cyclopropyl intermediates. X-Ray molecular structure of 3(4→18)-abeo-17-noraphidicol-2,18(4)-dien-16-one

J. R. Hanson, P. B. Hitchcock and B. L. Yeoh, J. Chem. Soc., Perkin Trans. 1, 1986, 639 DOI: 10.1039/P19860000639

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements