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Issue 0, 1981
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Controlling the outcome of a carbocation-initiated cyclisation

Abstract

The allylsilane, 6,6-dimethoxy-2-(trimethylsilylmethyl)hex-1-ene (2) gives 3-methylenecyclohexyl methyl ether (7) on treatment with tin(IV) chloride, whereas cyclisation of the corresponding compound without the silyl group (1) was known to give five products (5)–(6). The synthesis of the allylsilane (2) is described.

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Article type: Paper
DOI: 10.1039/P19810000251
Citation: J. Chem. Soc., Perkin Trans. 1, 1981,0, 251-255
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    Controlling the outcome of a carbocation-initiated cyclisation

    I. Fleming and A. Pearce, J. Chem. Soc., Perkin Trans. 1, 1981, 0, 251
    DOI: 10.1039/P19810000251

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