Twelve new fluorinated β-thioxo-ketones have been prepared from the corresponding fluorinated acetophenones and appropriate O-alkyl thioesters in the presence of sodamide, and have been characterized as copper chelates. These β-thioxo-ketones exist entirely in the hydrogen-bonded enol form ArC(OH)CH·CSR, as evidenced by i.r. and n.m.r. spectra.
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Journal of the Chemical Society, Perkin Transactions 1
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