Issue 13, 2017

Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

Abstract

An effective method for the synthesis of multi-substituted β-keto thioethers via Stevens rearrangement of simple β-keto thioethers with arynes has been developed. In these reactions, successive C–S/C–H/C–C bonds were formed in one pot under mild and transition-metal free conditions to afford multi-substituted β-keto thioethers in moderate to good yields.

Graphical abstract: Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

Supplementary files

Article information

Article type
Communication
Submitted
06 Feb 2017
Accepted
01 Mar 2017
First published
02 Mar 2017

Org. Biomol. Chem., 2017,15, 2716-2720

Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

X. Xu, Z. Lin, Y. Liu, J. Guo and Y. He, Org. Biomol. Chem., 2017, 15, 2716 DOI: 10.1039/C7OB00277G

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