Issue 42, 2016

A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

Abstract

A xanthene derivative containing a borinate moiety emitted red fluorescence with a high quantum yield. The interaction between the borinate and a sugar molecule induced a fluorescence change based on the change in the HOMO–LUMO gap. The response was pH-resistant in a wide range. In addition, catechol quenched through photoinduced electron transfer. The red fluorescence and polyol binding ability of dyes will pave the way for new biological applications of chemical sensors.

Graphical abstract: A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

Supplementary files

Article information

Article type
Paper
Submitted
06 Aug 2016
Accepted
27 Sep 2016
First published
27 Sep 2016
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2016,14, 10031-10036

A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

N. Shimomura, Y. Egawa, R. Miki, T. Fujihara, Y. Ishimaru and T. Seki, Org. Biomol. Chem., 2016, 14, 10031 DOI: 10.1039/C6OB01695B

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