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Issue 40, 2015
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Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases

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Abstract

Efficient conversion of ketones into kinetic enol phosphates under mild and accessible conditions has been realised using the developed methods with di-tert-butylmagnesium and bismesitylmagnesium. Optimisation of the quench protocol resulted in high yields of enol phosphates from a range of cyclohexanones and aryl methyl ketones, with tolerance of a range of additional functional units.

Graphical abstract: Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases

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Publication details

The article was received on 04 Sep 2015, accepted on 16 Sep 2015 and first published on 21 Sep 2015


Article type: Communication
DOI: 10.1039/C5OB01849H
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2015,13, 10131-10135
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    Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases

    W. J. Kerr, D. M. Lindsay, V. K. Patel and M. Rajamanickam, Org. Biomol. Chem., 2015, 13, 10131
    DOI: 10.1039/C5OB01849H

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