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Issue 41, 2015
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Direct oxidative coupling of amidine hydrochlorides and methylarenes: TBHP-mediated synthesis of substituted 1,3,5-triazines under metal-free conditions

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Abstract

Various 2,4,6-trisubstituted 1,3,5-triazines were smoothly formed via TBHP-mediated direct oxidative coupling of amidine and methylarenes. This tandem oxidation–imination–cyclization transformation exhibits a straightforward protocol to prepare 1,3,5-triazines from easily available starting materials and green oxidants under metal-free conditions.

Graphical abstract: Direct oxidative coupling of amidine hydrochlorides and methylarenes: TBHP-mediated synthesis of substituted 1,3,5-triazines under metal-free conditions

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Publication details

The article was received on 28 Aug 2015, accepted on 15 Sep 2015 and first published on 15 Sep 2015


Article type: Communication
DOI: 10.1039/C5OB01799H
Citation: Org. Biomol. Chem., 2015,13, 10285-10289
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    Direct oxidative coupling of amidine hydrochlorides and methylarenes: TBHP-mediated synthesis of substituted 1,3,5-triazines under metal-free conditions

    W. Guo, Org. Biomol. Chem., 2015, 13, 10285
    DOI: 10.1039/C5OB01799H

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