Issue 39, 2015
From the journal:

Organic & Biomolecular Chemistry

Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates†

Satyanarayana Battula,ab   Atul Kumarab  and  Qazi Naveed Ahmed*ab  

* Corresponding authors

a Medicinal Chemistry Division, Indian Institute of Integrative Medicine (IIIM), Jammu, India

b Academy of Scientific and Innovative Research (AcSIR Fax: +91-1912569333), 2-Rafi Marg, New Delhi, India
E-mail: naqazi@iiim.ac.in

Abstract

The potential of TBHP to promote oxidative hydroxylation of α-hydroxy-β-oxophosphonates (HOPs) through C(CO)–C bond cleavage is described. This cleavage, as depicted in the mechanism is expected through an isomer of HOP that reacts with TBHP to generate acids.

Graphical abstract: Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

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Article information

DOI
https://doi.org/10.1039/C5OB01615K
Article type
Communication
Submitted
03 Aug 2015
Accepted
03 Sep 2015
First published
03 Sep 2015

Org. Biomol. Chem., 2015,13, 9953-9956

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Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

S. Battula, A. Kumar and Q. N. Ahmed, Org. Biomol. Chem., 2015, 13, 9953 DOI: 10.1039/C5OB01615K

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