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Issue 39, 2015
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Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

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Abstract

The potential of TBHP to promote oxidative hydroxylation of α-hydroxy-β-oxophosphonates (HOPs) through C(CO)–C bond cleavage is described. This cleavage, as depicted in the mechanism is expected through an isomer of HOP that reacts with TBHP to generate acids.

Graphical abstract: Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

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Publication details

The article was received on 03 Aug 2015, accepted on 03 Sep 2015 and first published on 03 Sep 2015


Article type: Communication
DOI: 10.1039/C5OB01615K
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Citation: Org. Biomol. Chem., 2015,13, 9953-9956
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    Metal-free oxidative cleavage of the C–C bond in α-hydroxy-β-oxophosphonates

    S. Battula, A. Kumar and Q. N. Ahmed, Org. Biomol. Chem., 2015, 13, 9953
    DOI: 10.1039/C5OB01615K

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