Issue 34, 2014
From the journal:

Organic & Biomolecular Chemistry

Copper catalyzed C–O bond formation via oxidative cross-coupling reaction of aldehydes and ethers†

Quan Wang,a   Hao Zheng,a   Wen Chai,a   Dianyu Chen,a   Xiaojun Zeng,a   Renzhong Fu*a  and  Rongxin Yuan*a  

* Corresponding authors

a School of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, 99 South 3rd Ring, Changshu, P. R. China
E-mail: renzhongfujs@126.com, yuanrx@cslg.edu.cn

Abstract

A practical and efficient construction of C–O bonds via oxidative cross-coupling reaction of aldehydes and ethers has been realized under open air. When 2 mol% copper was used as the catalyst, various α-acyloxy ethers were obtained with up to 93% isolated yield.

Graphical abstract: Copper catalyzed C–O bond formation via oxidative cross-coupling reaction of aldehydes and ethers

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Article information

DOI
https://doi.org/10.1039/C4OB00862F
Article type
Communication
Submitted
27 Apr 2014
Accepted
17 Jun 2014
First published
18 Jun 2014

Org. Biomol. Chem., 2014,12, 6549-6553

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Copper catalyzed C–O bond formation via oxidative cross-coupling reaction of aldehydes and ethers

Q. Wang, H. Zheng, W. Chai, D. Chen, X. Zeng, R. Fu and R. Yuan, Org. Biomol. Chem., 2014, 12, 6549 DOI: 10.1039/C4OB00862F

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