Issue 39, 2013

Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

Abstract

Enyne alcohols can react as precursors of either dienes or dienophiles with different substrates after hydroxylation and isomerization by gold catalysis. As such, oxa-bridged tricyclo[5.2.2.02,6]undec-8-ene-3,5-dione derivatives have been obtained by the Diels–Alder reaction and tetrahydro-1H-furo[3,4-c]pyran derivatives could be accessed by the hetero-Diels–Alder cycloaddition.

Graphical abstract: Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2013
Accepted
15 Aug 2013
First published
15 Aug 2013

Org. Biomol. Chem., 2013,11, 6707-6712

Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

R. Guo, K. Li and L. Gong, Org. Biomol. Chem., 2013, 11, 6707 DOI: 10.1039/C3OB41611A

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