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Issue 40, 2013
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The influence of G-quadruplex structure on DNA-based asymmetric catalysis using the G-quadruplex-bound cationic porphyrin TMPyP4·Cu

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Abstract

The DNA G-quadruplex-binding porphyrin TMPyP4·Cu was found to form efficient hybrid catalysts for DNA-based asymmetric catalysis when bound to DNA G-quadruplexes. Nucleobase substitution experiments using human telomere-derived G-quadruplex sequences suggest binding of the porphyrin on the 3′-face.

Graphical abstract: The influence of G-quadruplex structure on DNA-based asymmetric catalysis using the G-quadruplex-bound cationic porphyrin TMPyP4·Cu

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Publication details

The article was received on 03 Jul 2013, accepted on 09 Aug 2013 and first published on 12 Aug 2013


Article type: Paper
DOI: 10.1039/C3OB41366G
Citation: Org. Biomol. Chem., 2013,11, 6940-6945
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    The influence of G-quadruplex structure on DNA-based asymmetric catalysis using the G-quadruplex-bound cationic porphyrin TMPyP4·Cu

    M. Wilking and U. Hennecke, Org. Biomol. Chem., 2013, 11, 6940
    DOI: 10.1039/C3OB41366G

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