Issue 42, 2012
From the journal:

Organic & Biomolecular Chemistry

Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins†

Katrien Bert,a   Timothy Noël,‡a   Wim Kimpe,a   Jan L. Goemana  and  Johan Van der Eycken*a  

* Corresponding authors

a Laboratory for Organic and Bioorganic Synthesis, Department of Organic Chemistry, Ghent University, Krijgslaan 281 (S.4), B-9000 Ghent, Belgium
E-mail: Johan.VanderEycken@UGent.be
Fax: +32 9 264 49 98

Abstract

A small library of chiral imidate–ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).

Graphical abstract: Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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Article information

DOI
https://doi.org/10.1039/C2OB25871D
Article type
Paper
Submitted
07 May 2012
Accepted
08 Aug 2012
First published
09 Aug 2012

Org. Biomol. Chem., 2012,10, 8539-8550

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Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

K. Bert, T. Noël, W. Kimpe, J. L. Goeman and J. Van der Eycken, Org. Biomol. Chem., 2012, 10, 8539 DOI: 10.1039/C2OB25871D

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