Issue 14, 2012
From the journal:

Organic & Biomolecular Chemistry

Molecular design of chiral quaternary ammonium polymers for asymmetric catalysis applications†

Md. Masud Parvez,a   Naoki Haraguchia  and  Shinichi Itsuno*a  

* Corresponding authors

a Department of Environmental and Life Sciences, Molecular Chemistry Division, Toyohashi University of Technology, Tempaku-cho, Toyohashi, Japan
E-mail: itsuno@ens.tut.ac.jp
Fax: +81-532-44-6813
Tel: +81-532-44-6813

Abstract

Repeated reaction between a chiral quaternary ammonium dimer and disodium disulfonate gave a chiral ionic polymer, which showed excellent catalytic activity in the asymmetric benzylation of N-diphenylmethylene glycine tert-butyl ester.

Graphical abstract: Molecular design of chiral quaternary ammonium polymers for asymmetric catalysis applications

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Article information

DOI
https://doi.org/10.1039/C2OB06909A
Article type
Paper
Submitted
12 Nov 2011
Accepted
07 Feb 2012
First published
07 Feb 2012

Org. Biomol. Chem., 2012,10, 2870-2877

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Molecular design of chiral quaternary ammonium polymers for asymmetric catalysis applications

Md. M. Parvez, N. Haraguchi and S. Itsuno, Org. Biomol. Chem., 2012, 10, 2870 DOI: 10.1039/C2OB06909A

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