Issue 2, 2012
From the journal:

Organic & Biomolecular Chemistry

Iron-catalyzed ene-type propargylation of diarylethylenes with propargyl alcohols†

Shiyong Peng,a   Lei Wanga  and  Jian Wang*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: chmwangj@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 1760

Abstract

The diarylalkenyl propargylic complex framework has been found in many natural products and medicinal regents. Herein, we have disclosed an unprecedented FeCl3 catalyzed ene-type reaction of propargylic alcohols with 1,1-diaryl alkenes which enabled us to furnish a diarylalkenyl propargylic complex framework in moderate to high chemical yields (up to 98%).

Graphical abstract: Iron-catalyzed ene-type propargylation of diarylethylenes with propargyl alcohols

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Article information

DOI
https://doi.org/10.1039/C1OB06456H
Article type
Communication
Submitted
25 Aug 2011
Accepted
20 Sep 2011
First published
21 Sep 2011

Org. Biomol. Chem., 2012,10, 225-228

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Iron-catalyzed ene-type propargylation of diarylethylenes with propargyl alcohols

S. Peng, L. Wang and J. Wang, Org. Biomol. Chem., 2012, 10, 225 DOI: 10.1039/C1OB06456H

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