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Issue 20, 2010
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Studies on highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides

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Abstract

A highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides in which proton served as the electrophile was reported. Through the X-ray diffraction study, it was concluded that the reaction may proceed via a 5-membered cyclic intermediate following by attack of the OH at the sulfur atom.

Graphical abstract: Studies on highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides

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Publication details

The article was received on 15 Apr 2010, accepted on 23 Jun 2010 and first published on 09 Aug 2010


Article type: Paper
DOI: 10.1039/C0OB00007H
Citation: Org. Biomol. Chem., 2010,8, 4554-4561
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    Studies on highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides

    Z. Fang, C. Zhou, C. Fu and S. Ma, Org. Biomol. Chem., 2010, 8, 4554
    DOI: 10.1039/C0OB00007H

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