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Issue 13, 2010
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Chiral sulfoxides as activators of allyl trichlorosilanes in the stereoselective allylation of aldehydes

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Abstract

Chiral aryl methyl sulfoxides proved to be efficient activators in the asymmetric allylation of aldehydes with allyl trichlorosilanes. High enantioselectivity was found in the case of electron-poor aldehydes. The high levels of diastereoselectivity and the detection of nonlinear effects have allowed the elucidation of some mechanistic aspects of the reaction.

Graphical abstract: Chiral sulfoxides as activators of allyl trichlorosilanes in the stereoselective allylation of aldehydes

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Publication details

The article was received on 15 Feb 2010, accepted on 20 Apr 2010, published on 17 May 2010 and first published online on 17 May 2010


Article type: Paper
DOI: 10.1039/C002988B
Citation: Org. Biomol. Chem., 2010,8, 3055-3059
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    Chiral sulfoxides as activators of allyl trichlorosilanes in the stereoselective allylation of aldehydes

    V. De Sio, A. Massa and A. Scettri, Org. Biomol. Chem., 2010, 8, 3055
    DOI: 10.1039/C002988B

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