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Issue 13, 2009
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A stereoselective synthesis of (+)-physoperuvine using a tandem aza-Claisen rearrangement and ring closing metathesis reaction

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Abstract

A stereoselective synthesis of (+)-physoperuvine, a tropane alkaloid from Physalis peruviana Linne has been developed using a one-pot tandem aza-Claisen rearrangement and ring closing metathesis reaction to form the key amino-substituted cycloheptene ring.

Graphical abstract: A stereoselective synthesis of (+)-physoperuvine using a tandem aza-Claisen rearrangement and ring closing metathesis reaction

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Publication details

The article was received on 14 Apr 2009, accepted on 06 May 2009 and first published on 13 May 2009


Article type: Communication
DOI: 10.1039/B907341H
Citation: Org. Biomol. Chem., 2009,7, 2678-2680
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    A stereoselective synthesis of (+)-physoperuvine using a tandem aza-Claisen rearrangement and ring closing metathesis reaction

    A. M. Zaed, M. D. Swift and A. Sutherland, Org. Biomol. Chem., 2009, 7, 2678
    DOI: 10.1039/B907341H

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