Issue 5, 2009
From the journal:

Organic & Biomolecular Chemistry

Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane†

Baoda Lin,a   Miaochang Liu,a   Zhishi Ye,a   Jinchang Ding,a   Huayue Wua  and  Jiang Cheng*a  

* Corresponding authors

a College of Chemistry & Materials Engineering, Wenzhou University, Mid. Xueyuan Rd., Wenzhou, P. R. China
E-mail: jiangcheng@wzu.edu
Fax: +86-577-88156826
Tel: +86-577-88156826

Abstract

A copper-catalyzed C–N bond forming reaction among aryl siloxane and primary, secondary amines as well as amides has been described. The reaction was conducted in the presence of P(C6F5)3 and 4 Å molecular sieves in CH2Cl2 at room temperature under O2. A catalytic amount of TBAF was employed to activate aryl siloxanes.

Graphical abstract: Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane

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Article information

DOI
https://doi.org/10.1039/B819510B
Article type
Paper
Submitted
03 Nov 2008
Accepted
21 Nov 2008
First published
20 Jan 2009

Org. Biomol. Chem., 2009,7, 869-873

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Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane

B. Lin, M. Liu, Z. Ye, J. Ding, H. Wu and J. Cheng, Org. Biomol. Chem., 2009, 7, 869 DOI: 10.1039/B819510B

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