Issue 24, 2008
From the journal:

Organic & Biomolecular Chemistry

Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine†

José Antonio Morales-Serna,a   Josep Llaveria,a   Yolanda Díaz,a   M. Isabel Matheua  and  Sergio Castillón*a  

* Corresponding authors

a Departamento de Química Analítica y Química Orgánica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain
E-mail: sergio.castillon@urv.net
Fax: +34 977 558446
Tel: +34 977 559556

Abstract

An asymmetric sulfur ylide reaction was employed to prepare an epoxide intermediate in a convergent manner. This epoxide was efficiently transformed into D-erythro-sphingosine.

Graphical abstract: Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine

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Article information

DOI
https://doi.org/10.1039/B814882A
Article type
Communication
Submitted
26 Aug 2008
Accepted
01 Oct 2008
First published
17 Oct 2008

Org. Biomol. Chem., 2008,6, 4502-4504

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Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine

J. A. Morales-Serna, J. Llaveria, Y. Díaz, M. I. Matheu and S. Castillón, Org. Biomol. Chem., 2008, 6, 4502 DOI: 10.1039/B814882A

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