Issue 22, 2008
From the journal:

Organic & Biomolecular Chemistry

Gold-catalyzed intermolecular addition of alcohols toward the allenic bond of 4-vinylidene-2-oxazolidinones†

Yoshikazu Horino,*a   Yasushi Takata,a   Ken Hashimoto,a   Shigeyasu Kuroda,a   Masanari Kimurab  and  Yoshinao Tamarub  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Science and Engineering, University of Toyama, Gofuku 3190, Toyama, Japan
E-mail: horino@eng.u-toyama.ac.jp
Fax: +81 76 445 6819
Tel: +81 76 445 6820

b Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1–14, Bunkyo, Nagasaki, Japan

Abstract

Gold catalyzed intermolecular addition of alcohols toward the proximal allenic double bond of 4-vinylidene-2-oxazolidinones gives hydroalkoxylation products, which can be easily converted into the corresponding novel spiro dihydrofuran or dihydropyran derivatives in high yield.

Graphical abstract: Gold-catalyzed intermolecular addition of alcohols toward the allenic bond of 4-vinylidene-2-oxazolidinones

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Article information

DOI
https://doi.org/10.1039/B808921C
Article type
Paper
Submitted
28 May 2008
Accepted
29 Jul 2008
First published
24 Sep 2008

Org. Biomol. Chem., 2008,6, 4105-4107

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Gold-catalyzed intermolecular addition of alcohols toward the allenic bond of 4-vinylidene-2-oxazolidinones

Y. Horino, Y. Takata, K. Hashimoto, S. Kuroda, M. Kimura and Y. Tamaru, Org. Biomol. Chem., 2008, 6, 4105 DOI: 10.1039/B808921C

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