Issue 1, 2006

Borrowing hydrogen: iridium-catalysed reactions for the formation of C–C bonds from alcohols

Abstract

Alcohols have been employed as substrates for C–C bond-forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner–Wadsworth–Emmons reaction, nitroaldol and aldol reactions. The ‘borrowed hydrogen’ is then returned to the alkene to form a C–C bond.

Graphical abstract: Borrowing hydrogen: iridium-catalysed reactions for the formation of C–C bonds from alcohols

Article information

Article type
Paper
Submitted
03 Aug 2005
Accepted
26 Oct 2005
First published
25 Nov 2005

Org. Biomol. Chem., 2006,4, 116-125

Borrowing hydrogen: iridium-catalysed reactions for the formation of C–C bonds from alcohols

Phillip. J. Black, G. Cami-Kobeci, M. G. Edwards, P. A. Slatford, M. K. Whittlesey and J. M. J. Williams, Org. Biomol. Chem., 2006, 4, 116 DOI: 10.1039/B511053J

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