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Issue 23, 2005
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Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

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Abstract

In this perspective we give an overview of enantioselective C–H activation at allylic sites by means of rhodium(II)-stabilized donor–acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.

Graphical abstract: Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

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Publication details

The article was received on 05 Jul 2005 and first published on 31 Oct 2005


Article type: Perspective
DOI: 10.1039/B509425A
Citation: Org. Biomol. Chem., 2005,3, 4176-4187
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    Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

    H. M. L. Davies and J. Nikolai, Org. Biomol. Chem., 2005, 3, 4176
    DOI: 10.1039/B509425A

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