Issue 14, 2004

The first series of chiral 2,2′:6′,2″-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes

Abstract

The first series of chiral 2,2′:6′,2″-terpyridine tri-N-oxide ligands have been developed; They were showed to be active Lewis base-catalysts for asymmetric allylation of aldehydes using allyltrichlorosilane with optimal results at 0 °C for electron-deficient aromatic aldehydes (yields up to 97% and enantioselectivities up to 86% ee).

Graphical abstract: The first series of chiral 2,2′:6′,2″-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes

Article information

Article type
Communication
Submitted
27 May 2004
Accepted
27 May 2004
First published
09 Jun 2004

Org. Biomol. Chem., 2004,2, 1967-1969

The first series of chiral 2,2′:6′,2″-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes

W. Wong, C. Lee, H. Leung and H. Kwong, Org. Biomol. Chem., 2004, 2, 1967 DOI: 10.1039/B407933G

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