Issue 14, 2003
From the journal:

Organic & Biomolecular Chemistry

Diastereoselective intramolecular SmI2–H2O–amine mediated couplings†

Anders Dahlén,a   Annika Peterssona  and  Göran Hilmersson*a  

* Corresponding authors

a Organic Chemistry, Department of Chemistry, Göteborg University, SE-412 96 Göteborg, Sweden
E-mail: hilmers@organic.gu.se
Fax: 46 31 772 3840
Tel: 46 31 772 2904

Abstract

The SmI2–H2O–amine mixture has been shown to be effective for intramolecular couplings providing diastereoselectivities of up to 100% de in the coupling of O-cyclohexenyliodophenol derivatives into heterocycles.

Graphical abstract: Diastereoselective intramolecular SmI2–H2O–amine mediated couplings

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Article information

DOI
https://doi.org/10.1039/B305428D
Article type
Communication
Submitted
15 May 2003
Accepted
11 Jun 2003
First published
18 Jun 2003

Org. Biomol. Chem., 2003,1, 2423-2426

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Diastereoselective intramolecular SmI2–H2O–amine mediated couplings

A. Dahlén, A. Petersson and G. Hilmersson, Org. Biomol. Chem., 2003, 1, 2423 DOI: 10.1039/B305428D

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