Stepwise syntheses and supramolecular assemblies of a series of polyoxovanadate hybrids with various architectures

Abstract

By controlling the terminal organic ligands, various fascinating supramolecular assemblies originating from hydrogen bonding interactions in different dimensions in a series of hexavanadate hybrids were synthesized via step-by-step organic modification. These hybrids were characterized, and their structures were determined by single-crystal X-ray diffraction. Moreover, the introduction of a rigid bridging ligand has a positive influence on the assembly of supramolecular architectures, providing a new vision for the design and synthesis of advanced inorganic–organic materials.