Issue 3, 2018
From the journal:

New Journal of Chemistry

Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes†

Jiao Li,a   Zan Yang,a   Tao Yang,*a   Jianmin Yia  and  Congshan Zhou ORCID logo *a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, P. R. China
E-mail: zhoucongsh@126.com, yangtaozcs@126.com

Abstract

Herein, a copper/TBHP catalyst system for the α-C–H acyloxylation of carbonyl compounds is developed using terminal alkynes as the acyloxy source. A variety of carbonyl compounds and terminal alkynes are tolerated in this reaction. In addition, its possible mechanism is proposed.

Graphical abstract: Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

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Article information

DOI
https://doi.org/10.1039/C7NJ03989A
Article type
Letter
Submitted
16 Oct 2017
Accepted
21 Dec 2017
First published
05 Jan 2018

New J. Chem., 2018,42, 1581-1584

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Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

J. Li, Z. Yang, T. Yang, J. Yi and C. Zhou, New J. Chem., 2018, 42, 1581 DOI: 10.1039/C7NJ03989A

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