Issue 2, 2017

Linking cobalt–water chains with cis-1,4-cyclohexanedicarboxylate bridges to form a 2D network exhibiting spin-canted antiferromagnetism

Abstract

A two-dimensional magnetic network, [Co(cis-CHDA)(μ2-H2O)(H2O)2]·2H2O (1), featuring one-dimensional water-bridged Co2+ chains that are linked by pure cis-1,4-cyclohexanedicarboxylate (cis-CHDA) bridges has been obtained. Magnetic studies show that 1 exhibits spin-canted antiferromagnetism with spin-glass behavior at low temperature.

Graphical abstract: Linking cobalt–water chains with cis-1,4-cyclohexanedicarboxylate bridges to form a 2D network exhibiting spin-canted antiferromagnetism

Supplementary files

Article information

Article type
Letter
Submitted
20 Oct 2016
Accepted
16 Dec 2016
First published
16 Dec 2016

New J. Chem., 2017,41, 457-461

Linking cobalt–water chains with cis-1,4-cyclohexanedicarboxylate bridges to form a 2D network exhibiting spin-canted antiferromagnetism

Z. Li, Y. Cao, X. Zhang, Y. Xu, G. Cao, F. Zhang, S. Li, F. Zhang and B. Zhai, New J. Chem., 2017, 41, 457 DOI: 10.1039/C6NJ03278H

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