Issue 8, 2015
From the journal:

New Journal of Chemistry

PMoA/MCM-41 catalyzed aza-Michael reaction: special effects of mesoporous nanoreactor on chemical equilibrium and reaction rate through surface energy transformation†

Kui Fan,a   Yonghai Hui,*a   Xinmei Hu,a   Wei Shi,b   Haixia Panga  and  Zhengfeng Xie*b  

* Corresponding authors

a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
E-mail: hyhai97@126.com

b College of Chemistry and Chemical Engineering, Southwest Petroleum University, 8 Xindu Road, Xindu, Chengdu, China
E-mail: xiezhf72@gmail.com

Abstract

PMoA/MCM-41, a heterogeneous catalyst, acts as a nanoreactor to catalyze the aza-Michael reaction of nitro-olefins with hydrazides. Experimentation showed that this mesoporous nanoreactor could affect chemical equilibrium and kinetics. The possible mechanisms were thoroughly studied, and the surface energy of PMoA/MCM-41 was demonstrated to promote the aza-Michael reaction.

Graphical abstract: PMoA/MCM-41 catalyzed aza-Michael reaction: special effects of mesoporous nanoreactor on chemical equilibrium and reaction rate through surface energy transformation

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Article information

DOI
https://doi.org/10.1039/C5NJ01507C
Article type
Letter
Submitted
14 Jun 2015
Accepted
17 Jun 2015
First published
19 Jun 2015

New J. Chem., 2015,39, 5916-5919

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PMoA/MCM-41 catalyzed aza-Michael reaction: special effects of mesoporous nanoreactor on chemical equilibrium and reaction rate through surface energy transformation

K. Fan, Y. Hui, X. Hu, W. Shi, H. Pang and Z. Xie, New J. Chem., 2015, 39, 5916 DOI: 10.1039/C5NJ01507C

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