Issue 1, 2014
From the journal:

New Journal of Chemistry

Homochiral 3D lanthanide camphorates with high thermal stability†

Ming-Ling Sun,a   Xin Zhang,a   Yuan-Yuan Huang,a   Qi-Pu Lin,a   Ye-Yan Qina  and  Yuan-Gen Yao*a  

* Corresponding authors

a Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: yyg@fjirsm.ac.cn
Fax: +86-591-83714946
Tel: +86-591-83711523

Abstract

Three isomorphous homochiral 3D lanthanide coordination polymers ([Ln(HCOO)(D-cam)]n, where Ln = Dy (1), Ho (2), Er (3)), featuring sra topology have been constructed from triple-strand helical {Ln–O}n rod SBUs and chiral D-cam spacers. Thermogravimetric analyses show the remarkable thermal stabilities of all three rigid lanthanide camphorate frameworks up to 450 °C.

Graphical abstract: Homochiral 3D lanthanide camphorates with high thermal stability

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Article information

DOI
https://doi.org/10.1039/C3NJ00981E
Article type
Letter
Submitted
22 Aug 2013
Accepted
30 Sep 2013
First published
03 Oct 2013

New J. Chem., 2014,38, 55-58

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Homochiral 3D lanthanide camphorates with high thermal stability

M. Sun, X. Zhang, Y. Huang, Q. Lin, Y. Qin and Y. Yao, New J. Chem., 2014, 38, 55 DOI: 10.1039/C3NJ00981E

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