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Issue 1, 2014
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Homochiral 3D lanthanide camphorates with high thermal stability

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Abstract

Three isomorphous homochiral 3D lanthanide coordination polymers ([Ln(HCOO)(D-cam)]n, where Ln = Dy (1), Ho (2), Er (3)), featuring sra topology have been constructed from triple-strand helical {Ln–O}n rod SBUs and chiral D-cam spacers. Thermogravimetric analyses show the remarkable thermal stabilities of all three rigid lanthanide camphorate frameworks up to 450 °C.

Graphical abstract: Homochiral 3D lanthanide camphorates with high thermal stability

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Publication details

The article was received on 22 Aug 2013, accepted on 30 Sep 2013 and first published on 03 Oct 2013


Article type: Letter
DOI: 10.1039/C3NJ00981E
Citation: New J. Chem., 2014,38, 55-58
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    Homochiral 3D lanthanide camphorates with high thermal stability

    M. Sun, X. Zhang, Y. Huang, Q. Lin, Y. Qin and Y. Yao, New J. Chem., 2014, 38, 55
    DOI: 10.1039/C3NJ00981E

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