Issue 3, 2013

Efficient desulfinylative cross-coupling of thiophene and furan sulfinates with aryl bromides in aqueous media

Abstract

This letter describes the development of an environmentally benign palladium-catalyzed cross-coupling reaction using heteroaromatic sulfinates as nucleophilic coupling partners in aqueous media. This method accesses aryl-substituted heteroaromatics in very good yields chemoselectively without the need for base, additives or co-catalysts.

Graphical abstract: Efficient desulfinylative cross-coupling of thiophene and furan sulfinates with aryl bromides in aqueous media

Supplementary files

Article information

Article type
Letter
Submitted
19 Dec 2012
Accepted
11 Jan 2013
First published
11 Jan 2013

New J. Chem., 2013,37, 589-592

Efficient desulfinylative cross-coupling of thiophene and furan sulfinates with aryl bromides in aqueous media

S. Sévigny and P. Forgione, New J. Chem., 2013, 37, 589 DOI: 10.1039/C3NJ41153B

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