Issue 12, 2013
From the journal:

New Journal of Chemistry

N,N′-Dibutylbarbituric acid as an acceptor moiety in push–pull chromophores†

Milan Klikar,a   Filip Bureš,*a   Oldřich Pytela,a   Tomáš Mikysek,b   Zdeňka Padělková,c   Alberto Barsella,d   Kokou Dorkenood  and  Sylvain Achellee  

* Corresponding authors

a Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, Czech Republic
E-mail: filip.bures@upce.cz
Fax: +420 46 603 7068
Tel: +420 46 603 7099

b Department of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, Czech Republic

c Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, Czech Republic

d Département d'Optique ultrarapide et de Nanophotonique, IPCMS-CNRS, 23 Rue du Loess, BP 43, Strasbourg Cedex 2, France

e Institut des Sciences Chimiques de Rennes UMR CNRS 6226, IUT de Lannion, rue Eduard Branly, BP 30219, Lannion Cedex, France

Abstract

Twelve novel D–π–A chromophores with the N,N′-dibutylbarbituric acid acceptor, the N,N-dimethylamino donor and a systematically extended π-linker were synthesized. The extent of intramolecular charge-transfer, structure–property relationships and nonlinear optical properties were further investigated by X-ray analysis, electrochemistry, UV/Vis absorption spectra, calculations and EFISH experiments.

Graphical abstract: N,N′-Dibutylbarbituric acid as an acceptor moiety in push–pull chromophores

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Article information

DOI
https://doi.org/10.1039/C3NJ00683B
Article type
Paper
Submitted
24 Jun 2013
Accepted
03 Oct 2013
First published
04 Oct 2013
This article is Open Access
Creative Commons BY-NC license

New J. Chem., 2013,37, 4230-4240

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N,N′-Dibutylbarbituric acid as an acceptor moiety in push–pull chromophores

M. Klikar, F. Bureš, O. Pytela, T. Mikysek, Z. Padělková, A. Barsella, K. Dorkenoo and S. Achelle, New J. Chem., 2013, 37, 4230 DOI: 10.1039/C3NJ00683B

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