Issue 6, 2011
From the journal:

New Journal of Chemistry

Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers†‡

Nicolas Louvain,a   Yohei Takashima,b   Susumu Kitagawa*abc  and  Shuhei Furukawa*ac  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: shuhei.furukawa@icems.kyoto-u.ac.jp

b Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp

c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815, Japan

Abstract

Reaction of Cd(OAc)2·2H2O with 4,4′-biphenyldithiol (H2bpdt) in different alkyldiamines at 105 °C gave single crystals of different 2D-layered cadmium thiolates metal–organic frameworks. The alkyldiamine acts both as a solvent and as a coordination-engineering agent to control the crystal growth and the dimensionality of the cadmium thiolate networks.

Graphical abstract: Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers

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Article information

DOI
https://doi.org/10.1039/C1NJ20042A
Article type
Paper
Submitted
20 Jan 2011
Accepted
12 Apr 2011
First published
10 May 2011

New J. Chem., 2011,35, 1265-1269

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Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers

N. Louvain, Y. Takashima, S. Kitagawa and S. Furukawa, New J. Chem., 2011, 35, 1265 DOI: 10.1039/C1NJ20042A

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