Issue 6, 2011
From the journal:

New Journal of Chemistry

Molecular [Co(iii)Co(ii)] × 2 assemblies of a new bis-phenol/pyrazolyl ligand†‡

Gavin A. Craig,a   José Sánchez Costa,a   David Aguilà,a   Leoní A. Barrios,a   Olivier Roubeau,b   Simon J. Teatc  and  Guillem Aromí*a  

* Corresponding authors

a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain
E-mail: guillem.aromi@qi.ub.es
Fax: +34 934907725
Tel: +34 934039760

b Instituto de Ciencia de Materiales de Aragón, CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, Zaragoza, Spain

c Advanced Light Source, Berkeley Laboratory, 1 Cyclotron Road, Berkeley, USA

Abstract

Use of a novel multinucleating ligand in aerobic reactions with Co(II) affords two novel coordination assemblies exhibiting a rare linear [CoIII2CoII2] structure and novel structural features. The magnetic exchange within these unprecedented moieties is investigated.

Graphical abstract: Molecular [Co(iii)Co(ii)] × 2 assemblies of a new bis-phenol/pyrazolyl ligand

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Article information

DOI
https://doi.org/10.1039/C0NJ00861C
Article type
Letter
Submitted
02 Nov 2010
Accepted
20 Dec 2010
First published
17 Jan 2011

New J. Chem., 2011,35, 1202-1204

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Molecular [Co(III)Co(II)] × 2 assemblies of a new bis-phenol/pyrazolyl ligand

G. A. Craig, J. S. Costa, D. Aguilà, L. A. Barrios, O. Roubeau, S. J. Teat and G. Aromí, New J. Chem., 2011, 35, 1202 DOI: 10.1039/C0NJ00861C

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