Bimetallic cyanido-bridged magnetic materials derived from manganese(iii) Schiff-base complexes and pentacyanidonitrosylferrate(ii) precursor†
Abstract
Three heterobimetallic MnIIIFeII complexes: [Mn(5-Br-salpn)(H2O)]2[Fe(CN)5NO]·2H2O (1), [{Mn(salen)}2Fe(CN)5NO]·2H2O (2) and [{Mn(saltmen)}4Fe(CN)5NO](ClO4)2·H2O·2CH3OH (3), have been synthesized by the reactions of MnIII/Schiff–base (SB) complexes, [Mn(SB)(H2O)]+, (SB being salen2− = N,N′-ethylenebis(salicylideneiminato) dianion; 5-Br-salpn2− = N,N′-1,3-propylenebis(5-bromosalicylideneiminato) dianion or saltmen2− = N,N′-(1,1,2,2-tetramethylethylene) bis(salicylideneiminato) dianion) with the [Fe(CN)5NO]2− building block.
- This article is part of the themed collection: 3rd International Symposium on Molecular Materials (MOLMAT)