A new 34-membered N6O4-donor macrocycle: synthetic, X-ray and solvent extraction studies

Abstract

The synthesis and crystal structure of a new 34-membered N₆O₄-donor macrocycle2 is reported. Solvent extraction experiments (water/chloroform) indicated that 2 acts as an efficient extractant towards silver(I) and zinc(II) at pH values beyond 6 while the extraction of iodide and chromate occurs below this pH. A competitive metal extraction experiment at pH 7.2 in which the perchlorate salts of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) were present together in the aqueous phase led to the following order of increasing extraction efficiency: cobalt(II) < nickel(II) < zinc(II) < copper(II) ∼ cadmium(II). A substantial synergistic enhancement of zinc(II) salt extraction was observed for a dual-host extraction system using the macrocycle2 as cation binder and the tripodal thiourea ligand 3 as anion receptor; in particular, a notable extraction of zinc(II) sulfate was obtained.