Issue 10, 2007

Gold-catalyzed cyclizations of alkyne propargylic acetates to 2,3-bis(alkylidene)cycloalkanones and their related benzene derivatives

Abstract

We report a new and highly-convenient Au-catalyzed cyclization of alkyne propargylic acetates leading to 2,3-bis(alkylidene)cyclohexanones and their cycloadditions with a pendant dienophile.

Graphical abstract: Gold-catalyzed cyclizations of alkyne propargylic acetates to 2,3-bis(alkylidene)cycloalkanones and their related benzene derivatives

Supplementary files

Article information

Article type
Letter
Submitted
10 Apr 2007
Accepted
08 Aug 2007
First published
20 Aug 2007

New J. Chem., 2007,31, 1719-1721

Gold-catalyzed cyclizations of alkyne propargylic acetates to 2,3-bis(alkylidene)cycloalkanones and their related benzene derivatives

C. H. Oh and A. Kim, New J. Chem., 2007, 31, 1719 DOI: 10.1039/B705320G

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