Issue 8, 2005
From the journal:

New Journal of Chemistry

Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound†

Alexey Y. Koposov,a   Victor N. Nemykin*a  and  Viktor V. Zhdankin*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota Duluth, Duluth, USA
E-mail: vnemykin@d.umn.edu (VNN); vzhdanki@d.umn.edu (VVZ)
Fax: +1 218 7267394
Tel: +1 218 7266729 (VNN); +1 218 7266902 (VVZ)

Abstract

Single crystal X-ray structures of two 2-iodylbenzenesulfonamides reveal a combination of intra- and intermolecular I⋯O interactions leading to a typical hexacoordinated and a unique heptacoordinated iodine(V) center.

Graphical abstract: Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound

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Article information

DOI
https://doi.org/10.1039/B506573A
Article type
Letter
Submitted
10 May 2005
Accepted
24 Jun 2005
First published
07 Jul 2005

New J. Chem., 2005,29, 998-1000

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Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(V) compound

A. Y. Koposov, V. N. Nemykin and V. V. Zhdankin, New J. Chem., 2005, 29, 998 DOI: 10.1039/B506573A

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