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Issue 2, 2003
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Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4)(O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10)(O3PCH2CH2CH2CH2PO3)(2H2O)]n

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Abstract

A helical chain of [Co(1,10-phen)2(V2O4)(O3PCH2CH2CH2PO3)]n (1) and a stepped chain of [{Co(1,10-phen)2}2(V4O10)(O3PCH2CH2CH2CH2PO3)(2H2O)]n (2) have been synthesized under hydrothermal conditions using [Co(1,10-phen)2]2+ as the metal-organic subunit and organic diphosphonate ligands of different lengths.

Graphical abstract: Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

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Publication details

The article was received on 30 Sep 2002, accepted on 21 Nov 2002 and first published on 12 Dec 2002


Article type: Letter
DOI: 10.1039/B209564E
Citation: New J. Chem., 2003,27, 230-232
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    Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

    R. Fu, S. Hu, Z. Fu, J. Zhang and X. Wu, New J. Chem., 2003, 27, 230
    DOI: 10.1039/B209564E

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