Issue 2, 2002
From the journal:

New Journal of Chemistry

First example of a dumbbell-like architecture containing M3L2 cages and terephthalate anions

Jian Fan,a   Wei-Yin Sun,*a   Taka-aki Okamura,b   Jin Xie,a   Wen-Xia Tanga  and  Norikazu Ueyamab  

* Corresponding authors

a Coordination Chemistry Institute, Nanjing, China
E-mail: sunwy@nju.edu.cn

b Department of Macromolecular Science, Osaka, Japan

Abstract

A novel complex [Ag3(titmb)2]2[1,4-C6H4(COO)2]3·23 H2O [titmb = 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene] contains two M3L2 cages and three terephthalate anions, one of which is embedded in the two cages to form a dumbbell-like architecture and shows photoluminescence in the solid state when the titmb reacts with [Ag(NH3)2]NO3, an individual M3L2 cage [Ag3(titmb)2][NO3]3·5 H2O without luminescent properties was obtained.

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Article information

DOI
https://doi.org/10.1039/B109141G
Article type
Letter
Submitted
05 Oct 2001
Accepted
07 Nov 2001
First published
06 Feb 2002

New J. Chem., 2002,26, 199-201

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First example of a dumbbell-like architecture containing M3L2 cages and terephthalate anions

J. Fan, W. Sun, T. Okamura, J. Xie, W. Tang and N. Ueyama, New J. Chem., 2002, 26, 199 DOI: 10.1039/B109141G

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