Issue 2, 2001
From the journal:

New Journal of Chemistry

[NiL]2[Fe(CN)6]·4H2O [L  =  3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane]: a novel three-dimensional iron(II)–nickel(II) cyanide-bridged bimetallic assembly with a vat-like structure

Tongbu Lu,*a   Hua Xiang,a   Chengyong Su,a   Peng Cheng,b   Zongwan Maoa  and  Liangnian Jia  

* Corresponding authors

a Department of Chemistry, Zhongshan Uniersity, Guangzhou, China
E-mail: cesltb@zsu.edu.cn

b Department of Chemistry, Nankai Uniersity, Tianjin, China

Abstract

Reaction of either [Fe(CN)6]3− or [Fe(CN)6]4− with a macrocyclic Ni(II) complex leads to the same product with a new type of 3-D structure, which shows a weak ferromagnetic interaction between the nearest Ni(II) ions through the diamagnetic Fe(II) ion.

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Article information

DOI
https://doi.org/10.1039/B007406N
Article type
Letter
Submitted
06 Sep 2000
Accepted
21 Nov 2000
First published
17 Jan 2001

New J. Chem., 2001,25, 216-217

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[NiL]2[Fe(CN)6]·4H2O [L  =  3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane]: a novel three-dimensional iron(II)–nickel(II) cyanide-bridged bimetallic assembly with a vat-like structure

T. Lu, H. Xiang, C. Su, P. Cheng, Z. Mao and L. Ji, New J. Chem., 2001, 25, 216 DOI: 10.1039/B007406N

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