Issue 8, 1998

Isolation of the first diselenadiazolyl complex, Pd3[PhCNSeSeN]2[PPh3]4·2PhMe

Abstract

The selenium–nitrogen radical PhCNSeSeN is shown to be partially associated in solution; it undergoes an oxidative addition reaction to Pd(PPh3)4via Se–Se bond cleavage, and the structure of the first diselenadiazolyl–metal complex, Pd3[PhCNSeSeN]2[PPh3]4 is reported.

Article information

Article type
Paper

New J. Chem., 1998,22, 763-765

Isolation of the first diselenadiazolyl complex, Pd3[PhCNSeSeN]2[PPh3]4·2PhMe

J. E. Davies, R. J. Less, I. May and J. M. Rawson, New J. Chem., 1998, 22, 763 DOI: 10.1039/A804234I

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