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An optically inactive cis-transoidal poly[(4-carboxyphenyl)acetylene] was found to form a predominantly one-handed helical conformation upon complexation with optically active amines and amino alcohols in the solid state, resulting in a characteristic induced circular dichroism in the polymer backbone region.
Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines
K. Maeda, K. Hatanaka and E. Yashima, Mendeleev Commun., 2004, 14, 231 DOI: 10.1070/MC2004v014n06ABEH002074
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