Issue 5, 2001

Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds

Abstract

In the title system, OCNXeOSO2CF3 is formed, which readily oxidises iodobenzene to [PhI+–NCO OTf]. The direct amination of aromatic substrates is possible with the use of XeF2–Me3SiNCO–CF3SO3H.

Article information

Article type
Paper

Mendeleev Commun., 2001,11, 172-173

Xenon difluoride–trimethylsilyl isocyanatetriflic acid as a new system for the amination of aromatic compounds

N. Sh. Pirkuliev, V. K. Brel, N. G. Akhmedov, N. S. Zefirov and P. J. Stang, Mendeleev Commun., 2001, 11, 172 DOI: 10.1070/MC2001v011n05ABEH001514

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