Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid have been synthesized for the first time and characterized by spectroscopic methods; nucleophilic reactions of dimethyl 1-fluoroaziridine-2,2-dicarboxylate, such as transesterification and amidation, occur predominantly at the carboxy group trans-oriented with respect to the N-substituent.
R. G. Kostyanovsky, I. I. Chervin, G. K. Kadorkina, K. N. Makarov, L. T. Lantzeva, V. V. Rozhkov and A. V. Prosyanik, Mendeleev Commun., 1997, 7, 54 DOI: 10.1070/MC1997v007n02ABEH000690
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