Issue 19, 2012

Ultrahigh density electrolytic nanoreactors composed of liquid crystalline block copolymer template: water-electrolysis-induced deposition of cerium oxyhydroxide nanorod array

Abstract

Microphase-separated polyethylene oxide (PEO) cylindrical domains of liquid crystalline block copolymer have been utilized as electrolytic nanoreactors without any specific treatment such as etching. PEO works as electrolytic medium for the electrolytic deposition of a cerium oxyhydroxide nanorod array with ultrahigh density (up to 7.0 × 1011 cm−2).

Graphical abstract: Ultrahigh density electrolytic nanoreactors composed of liquid crystalline block copolymer template: water-electrolysis-induced deposition of cerium oxyhydroxide nanorod array

Supplementary files

Article information

Article type
Communication
Submitted
24 Dec 2011
Accepted
29 Mar 2012
First published
10 Apr 2012

J. Mater. Chem., 2012,22, 9477-9480

Ultrahigh density electrolytic nanoreactors composed of liquid crystalline block copolymer template: water-electrolysis-induced deposition of cerium oxyhydroxide nanorod array

T. Goda and T. Iyoda, J. Mater. Chem., 2012, 22, 9477 DOI: 10.1039/C2JM16818A

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