Issue 28, 2008
From the journal:

Journal of Materials Chemistry

The first organic paramagnetic metal containing the aminoxyl radical†

Hiroki Akutsu,*a   Keiko Sato,a   Shinji Yamashita,a   Jun-ichi Yamada,a   Shin'ichi Nakatsujia  and  Scott S. Turnerb  

* Corresponding authors

a Graduate School of Material Science, University of Hyogo, 3-2-1, Kouto, Kamigori-cho, Ako-gun, Hyogo, Japan
E-mail: akutsu@sci.u-hyogo.ac.jp
Fax: +81 791 58 0164
Tel: +81 791 58 0164

b Department of Chemistry, Warwick University, Gibbet Hill Road, Coventry, UK

Abstract

We have prepared an organic magnetic anion, PROXYL-4-CONHCH2SO3− (1). The electrocrystallisation of BEDT-TTF with PPh41 gave the first purely organic paramagnetic metal, β″-(BEDT-TTF)2(1). The salt shows a broad metal–insulator transition at approximately 210 K.

Graphical abstract: The first organic paramagnetic metal containing the aminoxyl radical

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Article information

DOI
https://doi.org/10.1039/B806694A
Article type
Communication
Submitted
21 Apr 2008
Accepted
10 Jun 2008
First published
18 Jun 2008

J. Mater. Chem., 2008,18, 3313-3315

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The first organic paramagnetic metal containing the aminoxyl radical

H. Akutsu, K. Sato, S. Yamashita, J. Yamada, S. Nakatsuji and S. S. Turner, J. Mater. Chem., 2008, 18, 3313 DOI: 10.1039/B806694A

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